Publication detail

Can electrodeposited Ti replace rolled Ti as substrate for the growth of anodic TiO2 nanotube layers?

SEPÚLVEDA SEPÚLVEDA, L. SOPHA, H. NORIKAWA, Y. HROMÁDKO, L. RODRIGUEZ PEREIRA, J. MAN, O. NOHIRA, T. YASUDA, K. MACÁK, J.

Original Title

Can electrodeposited Ti replace rolled Ti as substrate for the growth of anodic TiO2 nanotube layers?

Type

journal article in Web of Science

Language

English

Original Abstract

This study conducted a deep investigation of TiO2 nanotube (TNT) layers of two different thicknesses anodically grown on electrodeposited Ti films. The Ti films were grown from molten salts on Ni foils. The structure of the starting metals was compared by XRD (X -Ray Diffraction) and EBSD (Electron Backscatter Diffraction analyses), which showed a strong orientation towards the titanium (101) for the electrodeposited substrate, compared to the rather polycrystalline structure of the rolled Ti. The photoelectrochemical and electrochemical properties of 1 mu m and 5 mu m thick TNT layers anodically grown on these substrates were examined and compared with TNT layers of the same thickness. No significant morphological and compositional differences were found using SEM (Scanning Electron Microscopy) and XPS (X-ray Photoelectron Spectroscopy) between the TNT layers grown on the two substrates. However, higher photocurrent densities and ICPE values were observed for TNT layers grown on electrodeposited Ti. An in-depth investigation using Cyclic Voltammetry (CV) and Electrochemical Impedance Spectroscopy (EIS) analyses showed increased conductivity of the TNT layers produced on electrodeposited Ti compared to their counterparts. The carrier density (ND) for the TNT layers on electrodeposited Ti, calculated from Mott-Schottky measurements, showed a higher doping level than the TNT layers grown on Ti foils. This increase in ND results in more optimal photoelectrochemical performance of the TNT layers grown on electrodeposited Ti. All in all, the results presented herein pave the way for the use of electrodeposited Ti, with all its inherent benefits, and allow the further study of its promising properties in a wide range of applications.

Keywords

Electrodeposited Ti; TiO2 nanotube layers; Anodization; Photoelectrochemical performance; Molten salts

Authors

SEPÚLVEDA SEPÚLVEDA, L.; SOPHA, H.; NORIKAWA, Y.; HROMÁDKO, L.; RODRIGUEZ PEREIRA, J.; MAN, O.; NOHIRA, T.; YASUDA, K.; MACÁK, J.

Released

1. 3. 2024

Publisher

PERGAMON-ELSEVIER SCIENCE LTD

Location

OXFORD

ISBN

1873-3859

Periodical

ELECTROCHIMICA ACTA

Year of study

479

Number

143877

State

United Kingdom of Great Britain and Northern Ireland

Pages count

9

URL

https://www.sciencedirect.com/science/article/pii/S001346862400121X?via%3Dihub

BibTex

@article{BUT188935,
  author="Lina Marcela {Sepúlveda Sepúlveda} and Hanna Ingrid {Sopha} and Yutaro {Norikawa} and Luděk {Hromádko} and Jhonatan {Rodriguez Pereira} and Ondřej {Man} and Toshiyuki {Nohira} and Kouji {Yasuda} and Jan {Macák}",
  title="Can electrodeposited Ti replace rolled Ti as substrate for the growth of anodic TiO2 nanotube layers?",
  journal="ELECTROCHIMICA ACTA",
  year="2024",
  volume="479",
  number="143877",
  pages="9",
  doi="10.1016/j.electacta.2024.143877",
  issn="1873-3859",
  url="https://www.sciencedirect.com/science/article/pii/S001346862400121X?via%3Dihub"
}

Responsibility: Ing. Marek Strakoš